1989 - Central, Logan
1990 - Logan
1991 - Tomah
1992 - Tomah
1993 - Tomah
1994 - Central, Logan
1995 - Tomah
1996 - Tomah
1997 - Sparta
1998 - Onalaska
1999 - Sparta, Tomah
2000 - Aquinas
2001 - Holmen
2002 - Aquinas, Sparta
2003 - Sparta
2004 - Sparta
2005 - Sparta
2006 - Aquinas, Sparta
2007 - Aquinas
2008 - Aquinas
2009 - Sparta
2010 - Sparta, Central
2011 - Sparta, Central
*Volleyball is the only sport in which all seven current Mississippi Valley Conference schools have won at least one championship.
Coaches of the Year (began being awarded in the fall of 2001)
2001 - Phil Gilbert, Holmen
2002 - Rick Klein, Onalaska
2003 - Sarah Walters, Sparta
2004 - Sarah Walters, Sparta
2005 - Jen Slusser, Sparta
2006 - Danielle George, Aquinas
2007 - Danielle George, Aquinas
2008 - Danielle George, Aquinas
2009 - Jen Slusser, Sparta
2010 - Amy Olson, Central
2011 - Amy Olson, Central